Pencil Lead Electrode Termodifikasi Lapisan Tipis Perak Untuk Deteksi Ion Logam Cd2+ Dengan Metode Voltammetri
Keywords:
pencil lead electrode, silver thin layer, cyclic voltammetry, Cd2+ Supporting ElectrolyteAbstract
Cd2+ metal ions are contaminants that threaten the environment and human health. The purpose of the study is to study the electrochemical responses of PLE and Ag/PLE to detect Cd2+ metal ions, as well as to determine the best supporting electrolyte condition for measuring Cd2+ ions. The cyclic voltometric method is used to modify the electrodes by depositing a thin layer of silver. The results of the study show that Ag/PLE is better for detecting Cd2+ ions compared to PLE. The optimum conditions were obtained with a supporting electrolyte of acetate buffer pH 4.
Downloads
References
Annu, Sharma, S., Jain, R., & Raja, A. N. (2020). Review—Pencil Graphite Electrode: An Emerging Sensing Material. Journal of The Electrochemical Society, 167(3), 037501. https://doi.org/10.1149/2.0012003jes
Afifah, R., & Sari, T. K. (2024). Pengaruh Supporting Electrolyte Terhadap Deteksi Ion Logam Pb2+ Menggunakan Pencil Lead Electrode Termodifikasi Lapisan Tipis Perak dengan Metode …. Jurnal Pendidikan Tambusai, 8, 17970–17976. https://jptam.org/index.php/jptam/article/view/14938%0Ahttps://jptam.org/index.php/jptam/article/download/14938/11406
Allen J. Bard dan Larry R. Faulkner. (2001). Electrochemical Methods: Fundamentals and Applications
David, I. G., Popa, D. E., & Buleandra, M. (2017). Pencil graphite electrodes: A versatile tool in electroanalysis. In Journal of Analytical Methods in Chemistry (Vol. 2017). Hindawi Limited. https://doi.org/10.1155/2017/1905968
Dickinson, E. J. F., Limon-Petersen, J. G., Rees, N. V., & Compton, R. G. (2009). How much supporting electrolyte is required to make a cyclic voltammetry experiment quantitatively ―diffusional‖? A theoretical and experimental investigation. Journal of Physical Chemistry C, 113(25), 11157–11171. https://doi.org/10.1021/jp901628h
Douglas A. Skoog, F. James Holler, Stanley R. Crouch. (2007). Principles of Instrumental Analysis
Kumala Sari, T., Riga, R., & Zubir, M. (2021). Pencil Lead Electrode Modified with Gold Thin Layer for Voltammetric Detection of Chromium(VI). Eksakta, 22, 145–153. http://www.eksakta.ppj.unp.ac.id/index.php/eksakta
Marzuki, N. I., Bakar, F. A., Salleh, A. B., Heng, L. Y., Yusof, N. A., & Siddiquee, S. (2012). Development of electrochemical biosensor for formaldehyde determination based on immobilized enzyme. International Journal of Electrochemical Science, 7(7), 6070–6081. https://doi.org/10.1016/s1452-3981(23)19462-4
M. Fontana and N. Greene, “Mars Fontana-Corrosion Engineering (www.iranidata.com).pdf.”p.nationalll, 1987
N. Elgrishi, K. J. Rountree, B. D. McCarthy, E. S. Rountree, T. T. Eisenhart, and J. L. Dempsey, “A Practical Beginner’s Guide to Cyclic Voltammetry,” J. Chem. Educ., vol. 95, no. 2, pp. 197-206, 2018, doi:10.1021/acs.jchemed.7b00361
Palisoc, S., Lee, E. T., Natividad, M., & Racines, L. (2018). Silver nanoparticle modified graphene paste electrode for the electrochemical detection of lead, cadmium and copper. International Journal of Electrochemical Science, 13(9), 8854–8866. https://doi.org/10.20964/2018.09.03
Phal, S., Nguyen, H., Berisha, A., & Tesfalidet, S. (2021). In situ Bi/Carboxyphenyl- Modified Glassy Carbon Electrode as a Sensor Platform for Detection of Cd2+ dan Pb2+ using Square Wave Anodic Stripping Voltametry. Sensing and Biosensing Research. https://doi.org/10.1016/j.sbsr.2021.100455
Safavi, A., Maleki, N., & Farjami, E. (2009). Electrodeposited silver nanoparticles on carbon ionic liquid electrode for electrocatalytic sensing of hydrogen peroxide. Electroanalysis, 21(13), 1533–1538. https://doi.org/10.1002/elan.200804577
Sarvestani, M. R. J., Madrakian, T., & Afkhami, A. (2023). Simultaneous electrochemical determination of Pb2+ and Cd2+ ions in food samples by a silver nanoparticle-COF composite modified glassy carbon electrode. Journal of Food Measurement and Characterization, 3505–3514. https://doi.org/0.1007/s11694- 023-01880-1
Shamspur, T., Sheikhshoaie, I., & Mashhadizadeh, M. H. (2005). Flame atomic absorption spectroscopy (FAAS) determination of iron(III) after preconcentration on to modified analcime zeolite with 5-((4- nitrophenylazo)-N-(2′,4′-dimethoxyphenyl))salicylaldimine by column method. Journal of Analytical Atomic Spectrometry, 20(5), 476–478.