Mineralogy and Geochemistry of Rare Earth Elements in Manganese Deposits in the Anabanua District, Barru Regency, South Sulawesi Province, Indonesia
DOI:
https://doi.org/10.25299/jgeet.2025.10.4.24882Keywords:
Rare Earth Element, manganese, Petrographic, XRD, ICP-OESAbstract
Research programmes on rare earth elements have not been widely carried out, especially on manganese deposits, even though manganese deposits also contain rare earth elements. Research on manganese mineralogy has been done before, however, research has not focused on rare earth metal elements found in manganese deposits, so further research is needed to find out the mineralogy, geochemistry, and gardes of rare earth metal elements in manganese deposits in the tropics. There are 3 methods of analysis at once, namely petrographic, XRD, and ICP-OES methods. The minerals found in manganese samples in the study area are: Albite, Chlorite, Plagioclase, Orthoclase, Quartz, Chlorite, Opaque, Pyrolusite, Muscovite, Diopside, Hematite, Rodochroite, Manganochromite and Manganite. Rare earth element levels in manganese deposits are Yttrium (8.7-35.5 ppm), Scandium (4-28 ppm), Lanthanum (5.3-122 ppm), Cerium (9.4-198 ppm), Praseodymium (1.3-23.6 ppm), Neodymium (690.9), Samarium (1.2-15. 4 ppm), Europium (0.6-3.5 ppm), Gadolinium (1.4-13.5 ppm), Terbium (0.241.75 ppm), Dysprosium (1.4-7.9 ppm), Holmium (0. 3-1.3 ppm), Erbium (0.8-3.2 ppm), Thulium (0.1-0.4 ppm), Ytterbium (0.8-2.4 ppm) and Lutetium (0.14-0.39 ppm). These results indicate that manganese deposits in Anabanua Village, Barru Regency, have the potential to be a source of LREE (La, Ce, Pr, Nd, and Sm) with concentrations exceeding those of several deposits around the world, making them worthy of consideration in strategic mineral exploration in Indonesia in general.
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References
Ahmed M.A., Mirza T. A, & Kalaitzidis, S.P., 2023. Petrography and geochemistry of the Baska Piwaza ore mineralization, Halgurd Mountain, Iraqi Kurdistan Region: Insights on the Genesis. Iraqi Geological Journal, 56 (2B), 114-136.
Addy, SK., 2022. Rare earth element composition of manganese nodules and micronodules from the northwest Atlantic [dataset bundled publication]. PANGAEA,
Ashok D, Harini BP. 2023. Spatial evaluation of the heavy metal iron in soil, pond water and its mobility into the muscles of zebrafish using ICP-OES. Agricultural Science Digest, 44(2): 382−387.
Al-Jubury, H. E., Agha, M. Y. T., & Aqrawi, A. M., 2023. Petrography and Geochemical Relationships of the Ultramafic Rocks in Galalah area within Erbil Governorate, NE Iraq. Iraqi Journal of Science, 228-252.
Ariansyah. M. R, Massinai, M. F. I., & Altin, M., 2020. Rock Types Classification and Distribution on Anabanua Village, Barru Regency, South Sulawesi. Jurnal Geomine, 8(1), 1-8.
Atwood D.A, 2013. The rare earth elements: fundamentals and applications, 629 p., John Wiley & Sons.
Burton. J, 2022. US Geological Survey releases-2022 list of critical minerals. USGS.
Cabral, A.R., Zeh, A., Vianna, N.C. et al., 2019. Molybdenum-isotope signals and cerium anomalies in Palaeoproterozoic manganese ore survive high-grade metamorphism. Sci Rep 9, 4570.
Chen K. 2016. Indirect determination of Sulfate in surface water and groundwater by inductively coupled plasma atomic emission spectrometry. Metallurgical Analysis, 36(9): 73−76. (in Chinese)
Duz, M.Z., Sagirdag, M., Celik, KS., Hasan, M.A., & Kilinc, E., 2016. Geochemical multi-element ICP-OES analysis of borehole waters from SE Anatolia, Atomic Spectroscopy, 37(2), 43-49.
Emsbo, P., McLaughlin, P.I., Breit, G.N., du Bray, E.A., & Koenig, A.E., 2015. Rare earth elements in sedimentary phosphate deposits: solution to the global REE crisis? Journal of Gondwana Research.
Farhadiyan S, Kiani A, Noghre N, et al. 2024. Assessment of trace elements in Iranian kefir samples by using ICP-OES technique. International Journal of Environmental Analytical Chemistry, 0306–7319.
Falah, D., 2009. Eksplorasi Mangan Palludda Desa Pattappa Kecamatan Pujananting Kabupaten Barru. Dinas Pertambangan dan Energi Kabupaten Barru.
Ghobadi, M. H. , Mousavi, S. , Heidari, M. & Rafie, B., 2015. The Prediction of the Tensile Strength of Sandstones from their petrographical properties using regression analysis and artificial neural network. Geopersia, 5(2), 177-187.
Humphries, M., 2011. Rare earth elements: The global supply chain, Specialist in energy policy, Congressional research service.
Ilieva D, A. Surleva, Murariu M, Drochioiu G., & M. M. A. Abdullah., 2018. Evaluation of ICP-OES method for heavy metal and metalloids determination in sterile dump material, Solid State Phenomena.
Jha, A., 2014. Rare Earth Materials: Properties and Applications. CRC Press.
Karlinasari, R., Rahardjo, P.P., & Dajaputra, A., 2023. The Mineral characteristic of tropical residual soil using X-Ray Diffraction (XRD) and Scan Electron Microscopy (SEM). Journal of Advanced Civil and Environmental Engineering, 6(1), 42-56.
Kupolati, D., Amosun, J., Olayanju, G., Oyebamiji, A., & Fagbemigun T., 2020. Geophysical and Petrographical Study of Apatapiti Charnockitic Rock, Akure, Southwestern Nigeria. Iraqi Journal of Science, 1328-1344.
Liu BB, Han M, Liu J, et al. 2022. Determination of total Sulfur in geothermal water by inductively coupled plasma-atomic emission spectrometry. Journal of Groundwater Science and Engineering, 10(3): 285−291.
Liu H, Pourret O, Guo H, Martinez RE, & Zouhri L., 2018. Impact of Hydrous Manganese and Ferric Oxides on the Behavior of Aqueous Rare Earth Elements (REE): Evidence from a Modeling Approach and Implication for the Sink of REE. International Journal of Environmental Research and Public Health. 15(12):2837.
Moriyama. T, Panigrahi, M. K., Pandit, D., & Watanabe, Y., 2008. Rare earth element enrichment in Late Archean manganese deposits from the Iron Ore Group, East India. Resource geology, 58(4), 402-413.
Mustafa, T.A., Mirza, T.A., & Kalaitzidis, S.P., 2023. Petrographical and geochemical features of sulfide mineralization in the Walash Group, Gallala Area, Kurdistan Region of Iraq. Iraqi Geological Journal, 56(2E), 19-36.
Ohta, A., & Kawabe, I., 2001. REE (III) adsorption onto Mn dioxide (δ-MnO2) and Fe oxyhydroxide: Ce (III) oxidation by δ-MnO2. Geochimica et Cosmochimica Acta, 65(5), 695-703.
Purawiardi, R., 2001. Endapan Unsur-unsur Tanah Jarang dan Batuan Granit, Majalah Metalurgi Volume 16 Nomor 1, Juni 2001, LIPI, Serpong.
Qiao YY, Zhang XW, Fu YG. 2022. Determination of trace elements in drinking water samples by atomic spectroscopy. Modern Food, 28(1): 142−144. (in Chinese)
Ranjbaran, M., Javanmard, S.R., & Sotohian, F., 2019. Petrography and Geochemistry of Quaternary travertines in the Ab-Ask region, Mazandaran Province-Iran. Geopersia, 9(2), 351-365.
Sasmaz, A., Zagnitko, V. M., & Sasmaz, B., 2020. Major, trace and rare earth element (REE) geochemistry of the Oligocene stratiform manganese oxide-hydroxide deposits in the Nikopol, Ukraine. Ore Geology Reviews, 126, 103772.
Simandl, G., 2014. Geology and market-dependent significance of rare earth element resources Mineral. Deposita, 49: 889–904.
Sufriadin, Nur. I, & Widodo, S., 2015. Studi Mineralogi dan Geokimia Endapan Mangan Daerah Paluda, Kabupaten Barru, Sulawesi Selatan, Proceeding, seminar nasional kebumian ke-8 academia-industry linkage.
Serrano, J.G., & O.C.D. Garcia, 1998. Ce3+ adsorption on hydrated MnO2 . J Radioanal Nucl Chem 230, 33–37.
Voica C, M.H. Kovacs, Dehelean A, Ristoiu D, & A. M. Iordache., 2012. ICP-MS determinations of heavy metalsin surface waters from Transylvania, Romanian Journal of Physics, 57(7-8), 1184-1193.
XU Hai, GAO Junbo, YANG Ruidong, DU Lijuan, LIU Zhichen, CHEN Jun, FENG Kangning, YANG Guanghai., 2020. Genesis for Rare Earth Elements Enrichment in the Permian Manganese Deposits in Zunyi, Guizhou Province, SW China[J]. Acta Geologica Sinica,94(1):90-102.
Yazdi, P., Kananian, A., Raeisi, D., & Modabberi, S., 2023. Geochemistry, petrogenesis and petrology of intrusive rocks in Shadan gold deposit, SW Birjand, Eastern Iran. Geopersia, 13(1), 33-48.
Y. K. Banakar, & P. Jauhari., 1994.Geochemical Trends in the Sediments and Manganese Nodules from a Part of the Central Indian Basin. Jour. Geol. Soc. India., 43 (5): 591–598.
Zou J, Yang Q, Luo W, et al. 2017. Determination of Sulfur and Boron in salt lake brine and salt products using inductively coupled plasma atomic emission spectrometry. Fine Chemical Intermediates, 47(1): 63−65. (in Chinese)
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